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  • 482625 - (S)-(+)-6,6′-Dibromo-1,1′-bi-2-naphthol

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482625 Sigma-Aldrich

(S)-(+)-6,6′-Dibromo-1,1′-bi-2-naphthol

98%

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Properties

Related Categories Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   OORIFUHRGQKYEV-UHFFFAOYSA-N
assay   98%
optical activity   [α]20/D +49°, c = 1.8 in THF
mp   195-199 °C (lit.)

Description

General description

(S)-(+)-6,6′-Dibromo-1,1′-bi-2-naphthol is an aromatic chiral Bronsted acid.

Application

(S)-(+)-6,6′-Dibromo-1,1′-bi-2-naphthol may be used in the synthesis of (2R,3S)-3-phenylisoserine hydrochloride. It may also be used in the synthesis of BINOL-derived chiral ligands with aryl substituents in the 6,6-positions. [BINOL=1,1′-bi-2-naphthol]

Packaging

250 mg in amber glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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