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494119 Sigma-Aldrich

Deoxo-Fluor®

Synonym: Bis(2-methoxyethyl)aminosulfur trifluoride

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Properties

Related Categories Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
InChI Key   APOYTRAZFJURPB-UHFFFAOYSA-N
density   1.2 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

For a review of recent work on nucleophilic fluorination of organic compounds with Deoxo-Fluor® and DAST, see Synthesis, 2002, 17, 2561.

One flask conversion of carboxylic acids to amides via the intermediacy of acyl fluorides.

Legal Information

Deoxo-Fluor is a registered trademark of Air Products & Chemicals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Contact with water liberates toxic gas., Reacts violently with water.
RIDADR 
UN 3094 4.3(8) / PGI
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin


Same Products - New Packaging
Protocols & Articles

Articles

Bis(2-methoxyethyl)aminosulfur Trifluoride (Deoxo-Fluor®)

Originally reported by Lal and coworkers in 1999,1 bis(2-methoxyethyl)aminosulfur trifluoride (Deoxo-Fluor®) has shown remarkable utility in organic synthesis as a thermally stable alternative to (di...
Mark Redlich
Aldrich ChemFiles 2008, 8.3, 3.
Keywords: Chromatography, Ligands, Organic synthesis, Purification

Reagents for Fluorination

The trifluoromethyl substituent has long been recognized for the positive influence it can have on the biological activity of molecules. Professor William Dolbier, Jr. (University of Florida) has dev...
Aldrich ChemFiles 2007, 7.1, 11.

Peer-Reviewed Papers
15

References

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