EMAIL THIS PAGE TO A FRIEND
494275 Sigma-Aldrich

Chloroform-d

"100%", 99.96 atom % D, contains 0.03 % (v/v) TMS

Synonym: Deuterochloroform

Purchase

Properties

Related Categories Alphabetical Listings, C, Chloroform, Chloroform-d, NMR Solvents,
InChI Key   HEDRZPFGACZZDS-MICDWDOJSA-N
isotopic purity   99.96 atom % D
assay   ≥99.00%
contains   0.03 % (v/v) TMS
impurities   ≤0.0100% water
water
refractive index   n20/D 1.444 (lit.)
bp   60.9 °C(lit.)
mp   −64 °C (lit.)
density   1.500 g/mL at 25 °C (lit.)
mass shift   M+1

Description

General description

Chloroform-d (deuterochloroform, CDCl3) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy.

Application

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d.

Packaging

10 g in ampule

10×0.75 mL in ampule

50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 1888 6.1 / PGIII
WGK Germany 
3

Dispensette™ S
Protocols & Articles

Articles

Pressure-Temperature Calculator for Solvents

*Calculations provide estimated results based on Antoine's Coefficients and their associated temperature range values. Antoine's Coefficients were obtained from the National Institute of Standards an...

Related Content

Pressure-Temperature Nomograph Interactive Tool

Use the interactive controls above to simplify calculations and improve the efficiency of your distillation or evaporation requirements.
Keywords: Evaporation, Vaporization

Properties of Solvents Table

The table below presents the physical characteristics of common solvents. Easily reference or compare solvent properties like boiling point, density, and refractive index all from one list.
Keywords: Gas chromatography, Green chemistry, High performance liquid chromatography, Melting, Solvents

Peer-Reviewed Papers
15

References

Related Products

accessory

Product #

Description

Add to Cart

Z693847 Scienceware® Break-Safe ampule opener

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?