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495492 Sigma-Aldrich

tert-Butyldimethyl(2-propynyloxy)silane

97%

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Properties

Related Categories Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal More...
InChI Key   ZYDKYFIXEYSNPO-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.429 (lit.)
bp   40 °C/8 mmHg(lit.)
density   0.84 g/mL at 25 °C (lit.)

Description

General description

tert-Butyldimethyl(2-propynyloxy)silane is an aliphatic terminal alkyne.

Application

tert-Butyldimethyl(2-propynyloxy)silane may be used in the synthesis of (R)-2,3-pentadecadien-1-ol and (S)-ethyl 5-(tert-butyldimethylsilyloxy)-2-hydroxy-2-phenylpent-3-ynoate.

Packaging

5, 25 mL in glass bottle

Safety & Documentation

Safety Information

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Functionalized Alkynes

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydrobor...
Matthias Junkers
ChemFiles 2008, 8.1, 14.
Keywords: 1,3-Dipolar cycloaddition, Addition reactions, Building blocks, Click chemistry, Cycloadditions, Favorskii Reaction, Metathesis, Nucleophilic additions, Nucleophilic substitutions, Substitutions

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Alkynes and Acetylenic Building Blocks

We list over 600 alkyne building blocks, including a wide array of propargyl alcohols, acetylenic boron reagents, and halogenated substrates for cross-coupling. Additionally, many of these are termin...
Keywords: Building blocks, Coupling reactions, Cross couplings

Peer-Reviewed Papers
15

References

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