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496383 Aldrich

1,10-Phenanthroline-5,6-dione

97%

Synonym: Stahl phd oxidant, phd

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Properties

Related Categories Building Blocks, C11 to C12, Carbonyl Compounds, Chemical Synthesis, Ketones,
InChI Key   KCALAFIVPCAXJI-UHFFFAOYSA-N
assay   97%
mp   260 °C (dec.)(lit.)

Description

Packaging

1 g in glass bottle

Application

1,10-Phenanthroline-5,6-dione may be used in the preparation of homo- and heterometallic complexes with early transition metal ions.

A Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst

General description

1,10-Phenanthroline-5,6-dione (phendio) forms Cu(II) and Ag(I) phendio complexes, which show potent anti-fungal and anti-cancer activity. The modification of glassy carbon (GC) electrodes with phendio complexes of transition metals leads to the catalytic oxidation of NADH at low overpotential.

Price and Availability


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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Stahl Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stahl Group – Professor Product Portal
Keywords: Aerobic, Catalysis, Dehydrogenation, Filtration, Oxidations, Pharmaceutical, Purification

Peer-Reviewed Papers
15

References

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