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497517 Sigma-Aldrich

Benzylzinc bromide solution

0.5 M in THF

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Properties

Related Categories Alkyl, Chemical Synthesis, Organometallic Reagents, Organozinc Halides, Rieke and Organozinc Reagents More...
concentration   0.5 M in THF
density   0.978 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   Br[Zn]Cc1ccccc1
InChI   1S/C7H7.BrH.Zn/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
InChI key   OQPRTUBCROVGHA-UHFFFAOYSA-M

Description

Application

Benzylzinc bromide solution can be used as a nucleophile for the Mannich-type synthesis of 1,2-diarylethylpiperazines. It can also undergo C−C cross coupling reactions with aryl halides.

Packaging

50 mL in Sure/Seal™

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 2056 3 / PGII
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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