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498475 Sigma-Aldrich

4-(Ethoxycarbonyl)phenylzinc iodide solution

0.5 M in THF

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Properties

Related Categories Aryl, Chemical Synthesis, Organometallic Reagents, Organozinc Halides, Rieke and Organozinc Reagents More...
Quality Level   100
concentration   0.5 M in THF
density   1.018 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   CCOC(=O)c1ccc([Zn]I)cc1
InChI   1S/C9H9O2.HI.Zn/c1-2-11-9(10)8-6-4-3-5-7-8;;/h4-7H,2H2,1H3;1H;/q;;+1/p-1
InChI key   QKMCGFIQAJUQIL-UHFFFAOYSA-M

Description

Application

4-(Ethoxycarbonyl)phenylzinc iodide can be used as:
• A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
• A starting material in the synthesis of indazole derived glucagon receptor antagonists.
• A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.

Packaging

50 mL in Sure/Seal™

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2056 3 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
1.0 °F - closed cup
Flash Point(C) 
-17.2 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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