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510017 Sigma-Aldrich

(Oxydi-2,1-phenylene)bis(diphenylphosphine)

Green Alternative

98%

Synonym: Bis[(2-diphenylphosphino)phenyl] ether, DPEPhos

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Properties

Related Categories 12 Principles Aligned Products, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Greener Catalysts,
Quality Level   100
assay   98%
reaction suitability   reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reagent type: ligand
reaction type: Heck Reaction
  reagent type: ligand
reaction type: Hydroaminations
  reagent type: ligand
reaction type: Negishi Coupling
  reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   184-187 °C (lit.)
functional group   phosphine
SMILES string   O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
InChI   1S/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
InChI key   RYXZOQOZERSHHQ-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Packaging

25 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Related Content

The 12 Principles of Green Chemistry

The aim of green chemistry is to reduce chemical related impact on human health and virtually eliminate contamination of the environment through dedicated, sustainable prevention programs. Green chem...
Keywords: Building blocks, Catalysis, Degradations, Derivatizations, Environmental, Green chemistry, Separation, Solvents

Peer-Reviewed Papers
15

References

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