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522554 Aldrich

2-Hydroxyphenylboronic acid pinacol ester

98%

Synonym: 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

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Properties

Related Categories Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   VLROJECCXBBKPZ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.506(lit.)
bp   282 °C(lit.)
density   1.05 g/mL at 25 °C(lit.)

Description

Application

Widely used in Suzuki coupling chemistry.

Reactant involved in:
• Synthesis of indolo-fused heterocyclic inhibitors of polymerase enzyme of hepatitis C
• Studies of pi-interactions, electronic structure and transient UV absorption of subphthalocyanine-borate-bridged ferrocene-fullerene conjugates
• Synthesis of subphthalocyanine and fused-ring nicotine derivatives
• Suzuki-Miyaura coupling-triflation sequence, reduction and salt formation for synthesis of hydroxylated oligoarene phosphines

Packaging

1, 5 g in glass bottle

Price and Availability


KitAlysis - Increasing Catalysis Productivity
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Arylboronic Acid-Pinacol Esters

The synthesis of biaryl compounds via the Suzuki coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura, et al. demonstrated t...
Chemfiles Volume 1 Article 1
Keywords: Coupling reactions, Suzuki coupling

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions

Peer-Reviewed Papers
15

References

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