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525693 Sigma-Aldrich

6-Bromo-2-pyridinecarboxaldehyde

97%

  • CAS Number 34160-40-2

  • Empirical Formula (Hill Notation) C6H4BrNO

  • Molecular Weight 186.01

  •  MDL number MFCD02683546

  •  PubChem Substance ID 24874502

  •  NACRES NA.22

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Properties

Related Categories Aldehydes, Building Blocks, C1 to C6, C6, Carbonyl Compounds,
Quality Level   100
assay   97%
mp   81-85 °C (lit.)
storage temp.   2-8°C
SMILES string   [H]C(=O)c1cccc(Br)n1
InChI   1S/C6H4BrNO/c7-6-3-1-2-5(4-9)8-6/h1-4H
InChI key   QWFHFNGMCPMOCD-UHFFFAOYSA-N

Description

General description

6-Bromo-2-pyridinecarboxaldehyde is a pyridine derivative. It participates in the synthesis of meso-substituted trans-A2B2-porphyrin.

Application

6-Bromo-2-pyridinecarboxaldehyde may be used in the synthesis of:
• 6-([2,2’-bi(1,3-dithiolylidene)]-4-yl)picolinaldehyde
• tris(2-pyridylmethyl)amine (Tpy) derivative having Tpy core bearing a 3-formyl-phenyl substituent on one of the three arms
• syn- and anti- forms of 4-(6-bromopyridin-2-yl)-3-methyl-3-phenyloxetan-2-one
• 6-(2,4,6-triisopropylphenyl)-2-pyridinecarboxaldehyde

Substrate used in a study of a rhodium-catalyzed, reductive aldol coupling with divinyl ketones leading to syn ß-hydroxyenones.

Useful building block for Tris[(pyridyl)methyl]amine ligands.

Packaging

1, 10 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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