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528897 Sigma-Aldrich

5-Bromo-2-iodotoluene

98%

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Properties

Related Categories Aryl, Building Blocks, C7, Chemical Synthesis, Halogenated Hydrocarbons,
Quality Level   100
assay   98%
refractive index   n20/D 1.65 (lit.)
bp   263 °C (lit.)
density   2.08 g/mL at 25 °C (lit.)
SMILES string   Cc1cc(Br)ccc1I
InChI   1S/C7H6BrI/c1-5-4-6(8)2-3-7(5)9/h2-4H,1H3
InChI key   GHTUADBHTFHMNI-UHFFFAOYSA-N

Description

General description

5-Bromo-2-iodotoluene is a halogenated hydrocarbon. It undergoes chemoselective Suzuki reaction with phenylboronic acid to yield the corresponding carboxylic acid.

Application

5-Bromo-2-iodotoluene may be used in the synthesis of:
• 2-bromo-5-(4-bromo-2-methylphenyl)-3-methylpyridine
• 4-bromo-4′-(carbazol-9-yl)-2-methylbiphenyl
• 4,4′-dibromo-2-methyl-biphenyl
• 3-methyl-4-phenylbromobenzene
• 4-(4-bromo-2-methylphenyl)butanoic acid

Packaging

100 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning-Warning
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
110 °C - closed cup

Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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