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529680 Sigma-Aldrich

Manganese(II) chloride hydrate

99.999% trace metals basis

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Manganese Catalysts, Manganese Salts,
Quality Level   100
assay   99.999% trace metals basis
reaction suitability   core: manganese
  reagent type: catalyst
mp   122 °C (lit.)
density   1.913 g/mL at 25 °C (lit.)
storage temp.   2-8°C
SMILES string   O.Cl[Mn]Cl
InChI   1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
InChI key   BXRRQHBNBXJZBQ-UHFFFAOYSA-L

Description

Packaging

25 g in poly bottle

5 g in glass bottle

Application

Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 2
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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