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  • 532126 - Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

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532126 Sigma-Aldrich

Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

97%

Synonym: Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium

  • CAS Number 100163-29-9

  • Empirical Formula (Hill Notation) C20H24Cl2Zr

  • Molecular Weight 426.53

  •  MDL number MFCD00672123

  •  PubChem Substance ID 24877859

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Zirconium Catalysts More...
Quality Level   100
assay   97%
reaction suitability   reagent type: catalyst
mp   267-271 °C (lit.)
SMILES string   Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
InChI   1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
InChI key   AKXWJOYQORUUHS-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Regiochemistry in Negishi carboaluminations
• Polymerization of olefins
• Diastereoselective intramolecular olefin alkylations
• Asymmetric carbomagnesiation
• Reduction of esters to alcohols
• Enantioselective synthesis of allylic amines

Packaging

500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Catalysts
Protocols & Articles
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