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540129 Sigma-Aldrich

(2S)-(+)-Glycidyl tosylate

98%

Synonym: (S)-(+)-Glycidyl p-toluenesulfonate, (S)-(+)-Oxirane-2-methanol p-toluenesulfonate

  • CAS Number 70987-78-9

  • Empirical Formula (Hill Notation) C10H12O4S

  • Molecular Weight 228.26

  •  Beilstein/REAXYS Number 3592143

  •  EC Number 417-210-7

  •  MDL number MFCD00064489

  •  PubChem Substance ID 24878443

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks More...
InChI Key   NOQXXYIGRPAZJC-VIFPVBQESA-N
assay   98%
mp   46-49 °C (lit.)
storage temp.   2-8°C

Description

Packaging

5, 25 g in glass bottle

Application

Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.

Legal Information

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
3
RTECS 
RR0510050
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

HKR Epoxides

One of the most effective and recent methods for obtaining several classes of chiral building blocks is Jacobsen’s hydrolytic kinetic resolution technique (HKR). The method provides general access to...
Aldrich ChemFiles 2005, 5.4, 17.
Keywords: Anti-inflammatory agents, Asymmetric synthesis, Building blocks, Chemfiles, Deprotonations, Ligands, Methods

Peer-Reviewed Papers
15

References

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