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547794 Sigma-Aldrich

Tris[N,N-bis(trimethylsilyl)amide]neodymium(III)

97%

Synonym: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt

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Properties

Related Categories CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics,
assay   97%
form   solid
mp   156-159 °C (lit.)
SMILES string   C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI   1S/3C6H18NSi2.Nd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChI key   LWKIKGQVWYVALF-UHFFFAOYSA-N

Description

Application

Reagent for synthesis of:
• Imidophosphinate complexes of lanthanides
• Neodymium methoxides containing thienyl substituents
• Phenylene-bridged binuclear organolanthanide complexes
• Near-infrared photoluminescent neodymium(III) complexes

Reagent for:
• Rare-earth metal carboxylate-based catalysts
• Regioselective C-H activation

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3396 4.1(4.3) / PGII
WGK Germany 
3
Flash Point(F) 
35.6 °F
Flash Point(C) 
2 °C

Documents

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