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547980 Sigma-Aldrich

Tris[N,N-bis(trimethylsilyl)amide]samarium(III)

98%

Synonym: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium

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Properties

Related Categories CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics,
InChI Key   MUFPZLRACJKLCI-UHFFFAOYSA-N
assay   98%
form   solid
mp   93-106 °C (lit.)
reaction suitability   reagent type: catalyst

Description

Application

Reactant for synthesis of:
• Heterobimetallic samarium(III) complexes
• Binuclear lanthanide complexes

Catalyst for:
• Coordination polymerization of renewable butyrolactone-based vinyl monomers
• Intramolecular hydroamination of non-activated alkenes
• Chiral functionalization of isoxazoles
• Enantioselective hydroamination / cyclization

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3396 4.1(4.3) / PGII
WGK Germany 
3
Flash Point(F) 
35.6 °F
Flash Point(C) 
2 °C

Documents

Certificate of Analysis

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Protocols & Articles
Peer-Reviewed Papers
15

References

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