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549800 Sigma-Aldrich

4-Bromo-2,3-dimethylanisole

96%

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Properties

Related Categories Building Blocks, C9, Chemical Synthesis, Ethers, Organic Building Blocks,
assay   96%
refractive index   n20/D 1.566 (lit.)
bp   197 °C (lit.)
density   1.36 g/mL at 25 °C (lit.)
SMILES string   COc1ccc(Br)c(C)c1C
InChI   1S/C9H11BrO/c1-6-7(2)9(11-3)5-4-8(6)10/h4-5H,1-3H3
InChI key   WOWNZZYJCUUIFC-UHFFFAOYSA-N

Description

General description

4-Bromo-2,3-dimethylanisole can be prepared from 2,3-dimethylanisole via bromination using N-bromosuccinimide-acetonitrile (NBS-CH3CN) system.

Application

4-Bromo-2,3-dimethylanisole may be used in the preparation of:
• 4,6-Dibromo-2,3-dimethylanisole via bromination using NBS-CH3CN system.
• 4-Methoxy-2,2′,3,3′-tetramethyldiphenyl ether by reacting with 2,3-dimethylphenol.
• A novel arylsulfonamide derivative with potent glucocorticoid receptor (GR) agonist activity.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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