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551198 Sigma-Aldrich

1-(4-Methylphenyl)-3-buten-1-ol

97%

Synonym: 1-p-Tolyl-but-3-en-1-ol

  • CAS Number 24165-63-7

  • Linear Formula CH3C6H4CH(OH)CH2CH=CH2

  • Molecular Weight 162.23

  •  MDL number MFCD03427119

  •  PubChem Substance ID 24879206

  •  NACRES NA.22

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Properties

Related Categories Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks More...
InChI Key   RCKGDEZXTBRGHR-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.5270 (lit.)
bp   253 °C (lit.)
density   0.983 g/mL at 25 °C (lit.)

Description

General description

1-(4-Methylphenyl)-3-buten-1-ol (1-p-tolyl-but-3-en-1-ol) is a homoallylic alcohol derivative. It can be prepared by the allylation of 4-methylbenzaldehyde using potassium allyltrifluoroborate in the presence of 18-crown-6. It can undergo Prins cyclization with in the presence of cellulose-sulfonic acid to form the corresponding tetrahydropyran-4-ol.

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
15

References

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