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555142 Sigma-Aldrich

1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene

  • CAS Number 95408-38-1

  • Empirical Formula (Hill Notation) C30H36FeP2

  • Molecular Weight 514.40

  •  MDL number MFCD03701526

  •  PubChem Substance ID 24879174

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
InChI Key   GQIMIFFIUZZVMJ-UHFFFAOYSA-N
mp   75-79 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Coupling Reactions

Description

Application

• Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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