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555967 Sigma-Aldrich

mono-Chloroborane dioxane complex

2.5 M in methylene chloride

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Properties

concentration   2.5 M in methylene chloride
SMILES string   Cl[BH2-][O+]1CCOCC1

Description

Application

Can readily substitute for common hydroborating reagents such as BH3 · THF and BMS.

Legal Information

U.S. Pat. No. 6,008,414

Safety & Documentation

Safety Information

RIDADR 
UN 3286 3/PG 2
WGK Germany 
2
Flash Point(F) 
34 °F
Flash Point(C) 
1 °C
Protocols & Articles

Articles

Chloroborane-dioxane Complexes

Hydroboration of various olefins using monochloroborane or dichloroborane is a common route to valuable synthetic intermediates, including amines, ketones, dienes, and boronic acids or esters.1 The m...
ChemFiles Volume 5 Article 9
Keywords: Applications, transformation

Peer-Reviewed Papers
15

References

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