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560871 Sigma-Aldrich

2-Methyl-2-propanesulfinamide

97%, racemic

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonamides/Sulfinamides, Sulfur Compounds More...
assay   97%
mp   97-101 °C (lit.)
storage temp.   2-8°C
SMILES string   CC(C)(C)S(N)=O
InChI   1S/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3
InChI key   CESUXLKAADQNTB-UHFFFAOYSA-N

Description

Application

Ellman′s Sulfinamides

Synthesis of 4-sulfonyliminopiperidine and its reaction with benzyl Grignard to form an important pharmaceutical building block, 4-benzyl-4-aminopiperidne. Also used to prepare spiro tosylaziridines via methylene insertion into the derived sulfonylimine.

Packaging

1, 5, 25 g in poly bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Ellman Group – Professor and Product Portal

From our library of Articles, Sigma-Aldrich presents Ellman Group – Professor and Product Portal
Keywords: Arylations, Asymmetric synthesis, C-C bond formation, Catalysis, Drug discovery, Ligands, Pharmaceutical

Related Content

Ellman's Sulfinamides in chemical Synthesis

Since its introduction by Ellman in 1997 as a chiral ammonia equivalent,1 enantiopure 2-methyl-2-propanesulfinamide (tert-butanesulfinamide) has been demonstrated to be a versatile chiral auxiliary a...
Keywords: Antibiotics, Asymmetric synthesis, Condensations, Cyclizations, Ligands, Reductions

Peer-Reviewed Papers
15

References

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