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561657 Sigma-Aldrich

(1,3-Dioxan-2-ylethyl)magnesium bromide solution

0.5 M in THF

  • CAS Number 480438-44-6

  • Empirical Formula (Hill Notation) C6H11BrMgO2

  • Molecular Weight 219.36

  •  MDL number MFCD00061518

  •  PubChem Substance ID 24879959

  •  NACRES NA.22

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Properties

Related Categories Alkyl, Aryl and Alkenyl - Grignard reagent, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
reaction suitability   reaction type: Grignard Reaction
concentration   0.5 M in THF
bp   65 °C
density   0.951 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   Br[Mg]CCC1OCCCO1
InChI   1S/C6H11O2.BrH.Mg/c1-2-6-7-4-3-5-8-6;;/h6H,1-5H2;1H;/q;;+1/p-1
InChI key   JYNXRXBIEHSSLR-UHFFFAOYSA-M

Description

Application

(1,3-Dioxan-2-ylethyl)magnesium bromide can be used:
• In a Grignard addition-acylation method for the preparation of enamides.
• To prepare trisubstituted allenes by reacting with propargylic ammonium salts.
• In one of the key synthetic steps for the synthesis of febrifugine based antimalarial drugs.

Packaging

50 mL in Sure/Seal™

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
WGK 3
Flash Point(F) 
No data available
Flash Point(C) 
No data available
Protocols & Articles
Peer-Reviewed Papers
15

References

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