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562076 Sigma-Aldrich

3,5-Dimethylphenylmagnesium bromide solution

0.5 M in THF

  • CAS Number 34696-73-6

  • Linear Formula (CH3)2C6H3MgBr

  • Molecular Weight 209.37

  •  MDL number MFCD01311497

  •  PubChem Substance ID 24880004

  •  NACRES NA.22

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Properties

Related Categories Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
Quality Level   100
reaction suitability   reaction type: Grignard Reaction
concentration   0.5 M in THF
bp   65 °C
density   0.950 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   Cc1cc(C)cc([Mg]Br)c1
InChI   1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1
InChI key   XPXQQJMQESWIKM-UHFFFAOYSA-M

Description

Application

3,5-Dimethylphenylmagnesium bromide solution can be used:
• As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.
• To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl2 catalyst.

Packaging

50 mL in Sure/Seal™

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
WGK 3
Flash Point(F) 
-0.0 °F - closed cup
Flash Point(C) 
-17.78 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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