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562246 Sigma-Aldrich

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide solution

0.5 M in THF

  • CAS Number 36637-44-2

  • Empirical Formula (Hill Notation) C11H13BrMgO2

  • Molecular Weight 281.43

  •  MDL number MFCD03427254

  •  PubChem Substance ID 24880020

  •  NACRES NA.22

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Properties

Related Categories Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
Quality Level   100
reaction suitability   reaction type: Grignard Reaction
concentration   0.5 M in THF
bp   65 °C
density   0.961 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   Br[Mg]c1ccc(OC2CCCCO2)cc1
InChI   1S/C11H13O2.BrH.Mg/c1-2-6-10(7-3-1)13-11-8-4-5-9-12-11;;/h2-3,6-7,11H,4-5,8-9H2;1H;/q;;+1/p-1
InChI key   OHPUQUBYKZJOLY-UHFFFAOYSA-M

Description

Application

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide can be used:
• In the preparation of C-2 and C-20-diaryl steroidal derivatives.
• As an intermediate in the synthesis of multiblock copolymers having fullerene backbone for possible applications in photovoltaic devices.

Packaging

50 mL in Sure/Seal™

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
WGK 3
Flash Point(F) 
1.4 °F - closed cup
Flash Point(C) 
< -17 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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