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564036 Sigma-Aldrich

3-Fluoro-4-methoxyphenylboronic acid

≥95%

Synonym: 3-Fluoro-4-methoxybenzeneboronic acid, 3-Fluoro-4-methyloxyphenylboronic acid, 4-Methoxy-3-fluorophenylboronic acid

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids,
InChI Key   IILGLPAJXQMKGQ-UHFFFAOYSA-N
assay   ≥95%
form   powder
mp   206-211 °C (lit.)

Description

General description

Contains varying amounts of anhydride

Application

Reactant for:
• Preparation of hydroxyphenylnaphthols as 17ß-hydroxysteroid dehydrogenase Type 2 inhibitors
• Regioselective Suzuki coupling
• Ruthenium-catalyzed arylation reactions
• Synthesis of amino-trimethoxyphenyl-aryl thiazoles as microtubule inhibitors and potential antitumors
• Rhodium catalyzed cyanation
• Petasis reaction

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

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