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567507 Sigma-Aldrich

2-Methoxy-5-methylphenylboronic acid

≥95%

Synonym: 5-Methyl-2-methoxyphenylboronic acid

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids,
assay   ≥95%
mp   92-97 °C (lit.)
SMILES string   COc1ccc(C)cc1B(O)O
InChI   1S/C8H11BO3/c1-6-3-4-8(12-2)7(5-6)9(10)11/h3-5,10-11H,1-2H3
InChI key   CSVKZOZMPSRLTC-UHFFFAOYSA-N

Description

Application

Reactant for:
• Coupling reactions
• Preparation of selective quinazolinyl-phenol inhibitors of CHK1 as potential antitumors and radioprotectants
• Rh-catalyzed asymmetric arylation of aldehydes
• Stereoselective hydroarylation reactions
• Suzuki-Miyaura cross-coupling

Packaging

1, 5 g in glass bottle

Other Notes

Contains varying amounts of anhydride

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

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