• USA Home
  • 576557 - 2-Aminophenylboronic acid pinacol ester

EMAIL THIS PAGE TO A FRIEND
576557 Sigma-Aldrich

2-Aminophenylboronic acid pinacol ester

≥95%

Synonym: 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

  • CAS Number 191171-55-8

  • Empirical Formula (Hill Notation) C12H18BNO2

  • Molecular Weight 219.09

  •  MDL number MFCD02179448

  •  PubChem Substance ID 24880867

  •  NACRES NA.22

Purchase

Properties

Related Categories Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
Quality Level   100
assay   ≥95%
form   powder
mp   63-68 °C (lit.)
SMILES string   CC1(C)OB(OC1(C)C)c2ccccc2N
InChI   1S/C12H18BNO2/c1-11(2)12(3,4)16-13(15-11)9-7-5-6-8-10(9)14/h5-8H,14H2,1-4H3
InChI key   ZCJRWQDZPIIYLM-UHFFFAOYSA-N

Description

Application

Reactant involved in synthesis of:
• Indolo[3,4-cd][1]benzazepines via Pictet-Spengler-type cyclizations
• Antimicrobial amphiphilic aryl peptideomimetics
• Pyridoquinazolines and benzo[h][1,6]naphthyridines via intramolecular electrophilic substitution reactions
• Thienopyridine derivatives
• Dihydroquinolones
• Methacrylamidophenylboronic acids

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions, Suzuki-Miyaura coupling

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?