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578703 Sigma-Aldrich

Dichloro(3-methyl-2-butenylidene)bis(tricyclopentylphosphine)ruthenium(II)

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Properties

Related Categories Catalysts for Polymerization, Materials Science, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization More...
form   solid
mp   94-96 °C (lit.)
storage temp.   2-8°C
SMILES string   Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(C1)P(C2CCCC2)C3CCCC3.C4CCC(C4)P(C5CCCC5)C6CCCC6
InChI   1S/2C15H27P.C5H8.2ClH.Ru/c2*1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;1-4-5(2)3;;;/h2*13-15H,1-12H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2
InChI key   UCDVULRIJNJVEV-UHFFFAOYSA-L

Description

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

• Reactant for synthesis of ruthenium olefin metathesis catalysts

• Catalyst for ring-opening metathesis polymerization

Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.

Other Notes

NO BULK ORDERS

Legal Information

US Patent No. 5,969,170 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For questions, please contact us at aldrich@sial.com

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany 
3
Protocols & Articles

Related Content

Metathesis in Chemical Synthesis

Olefin metathesis is now a well-entrenched synthetic technique, and is a powerful method for the clean construction of innumerable classes of chemical architectures. The broadly accepted belief that ...
Keywords: Building blocks, Cross metathesis, Enyne metathesis, Exothermic, Isomerizations, Ligands, Living polymerization, Metathesis, Olefin metathesis, Organic synthesis, Polymerization reactions, Ring opening metathesis polymerisation, Ring-closing metathesis

Peer-Reviewed Papers
15

References

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