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593230 Aldrich

Phenyllithium solution

1.9 M in dibutyl ether

Synonym: PhLi

  • CAS Number 591-51-5

  • Empirical Formula (Hill Notation) C6H5Li

  • Molecular Weight 84.04

  •  Beilstein Registry Number 506502

  •  MDL number MFCD00014254

  •  PubChem Substance ID 24881428

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Properties

Related Categories Aryl, Chemical Synthesis, Organolithium, Organometallic Reagents
InChI Key   NHKJPPKXDNZFBJ-UHFFFAOYSA-N
concentration   1.9 M in dibutyl ether
density   0.835 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

50, 100, 800 mL in Sure/Seal™

Application

Phenyllithium solution can be used to synthesize:
• 1-Acetyl-1′-diphenylphosphinoferrocene from ferrocenophane.
• Ethyl 2-acetylimino-1-benzyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from ethyl 1-benzyl-6-bromo-2-imino-1,2-dihydroquinoline-3-carboxylate.
• Ethyl 2-amino-1-benzoyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from (E)-ethyl 2-(acetylimino)-1-benzoyl-6-bromo-1,2-dihydroquinoline-3-carboxylate.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3392 4.2 / PGI
WGK Germany 
3
Flash Point(F) 
77 °F
Flash Point(C) 
25 °C

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