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594334 Sigma-Aldrich

Benzenecyclopentadienyliron(II) hexafluorophosphate

  • CAS Number 12176-31-7

  • Empirical Formula (Hill Notation) C11H11F6FeP

  • Molecular Weight 344.01

  •  MDL number MFCD05664319

  •  PubChem Substance ID 24881498

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron Catalysts More...
form   solid
mp   268 °C (dec.) (lit.)
SMILES string   [Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F
InChI   1S/C6H6.C5H5.F6P.Fe/c1-2-4-6-5-3-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h1-6H;1-5H;;/q;;-1;+1
InChI key   ZFDATMJBJWNTMT-UHFFFAOYSA-N

Description

Application

Catalyst for:
• Nitroxide-mediated photochemical-living radical polymerization reactions
• Assembly of complex photonic crystals
• Preparation of cyclopentadien-iron-biphenyl hexafluorophosphate ([Cp-Fe-biphenyl]+PF6-) for cationic photopolymerization of epoxy systems

Reactant for:
• LIgand exchange reactions
• Solid-state synthesis of carbon nanostructures

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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