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594539 Sigma-Aldrich

4-Methoxycarbonylphenylboronic acid

≥95%

Synonym: (4-Carbomethoxyphenyl)boronic acid, 4-Carbomethoxybenzeneboronic acid, 4-Methoxycarbonylbenzeneboronic acid, 4-borono-benzoic acid 1-methyl ester, p-(Methoxycarbonyl)boronic acid, p-(Methoxycarbonyl)phenylboronic acid, p-borono-benzoic acid methyl ester, Methyl 4-boronobenzoate, Methyl p-boronobenzoate

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   PQCXFUXRTRESBD-UHFFFAOYSA-N
assay   ≥95%
form   powder
mp   197-200 °C (lit.)

Description

Application

Reagent used for
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides
• One-pot ipso-nitration of arylboronic acids
• Copper-catalyzed nitration
• Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling


• Reagent used in Preparation of
• Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid
• Chromenones and their bradykinin B1 antagonistic activit
• Pt nanoparticles@Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injectio
• Salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor

Packaging

1, 5 g in glass bottle

Other Notes

Contains varying amount of anhydride

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Boronic Acids - ChemFiles 2007

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
ChemFiles 2007, 7.7, 3.
Keywords: Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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