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597252 Sigma-Aldrich

(S)-(+)-1,1′-Bi-2-naphthyl ditosylate

97%

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Properties

Related Categories Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   BKYJBVWKVKRIDN-UHFFFAOYSA-N
assay   97%
optical activity   [α]20/D +29°, c = 1% in chloroform
optical purity   ee: 98% (HPLC)
mp   177-181 °C (lit.)
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

BINOL and Derivatives

BINOL and its derivatives are one of the mostly widely used classes of ligands in asymmetric synthesis; being utilized in a broad array of reactions including: Diels–Alder, carbonyl addition and redu...
William Sommer and Daniel Weibel
Aldrich ChemFiles 2008, 8.2, 56.
Keywords: Addition reactions, Alkylations, Amidations, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Diels-Alder reaction, Ligands, Methods, Organic synthesis, Reductions

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