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597910 Sigma-Aldrich

(4-Chlorophenyl)triethoxysilane

97%

Synonym: 1-Chloro-4-triethoxysilylbenzene

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Properties

Related Categories Chemical Synthesis, Organometallic Reagents, Organosilicon, Trialkoxysilanes
Quality Level   100
assay   97%
refractive index   n20/D 1.474 (lit.)
bp   82-84 °C/0.07 mmHg (lit.)
density   1.069 g/mL at 25 °C (lit.)
SMILES string   CCO[Si](OCC)(OCC)c1ccc(Cl)cc1
InChI   1S/C12H19ClO3Si/c1-4-14-17(15-5-2,16-6-3)12-9-7-11(13)8-10-12/h7-10H,4-6H2,1-3H3
InChI key   AFILDYMJSTXBAR-UHFFFAOYSA-N

Description

Packaging

1, 5 g in glass bottle

Application

A silicon-based nucleophile shown to be reactive in Pd-catalyzed cross-coupling reactions.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
> 110 °C - closed cup
Protocols & Articles

Articles

New Alkoxysilanes for C–C Coupling Reactions

The use of silicon compounds as transmetalation reagents has attracted much attention as a viable alternative to the popular Stille and Suzuki coupling reactions mainly due to the formation of nontox...
Chemfiles Volume 3 Article 5
Keywords: Coupling reactions, Suzuki coupling, Transmetalation

Peer-Reviewed Papers
15

References

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