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611646 Sigma-Aldrich

Methanol-d4

≥99.8 atom % D, contains 0.05 % (v/v) TMS

Synonym: Methyl-d3 alcohol d, Tetradeuteromethanol

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Properties

Related Categories Alphabetical Listings, M, Methanol-d4, NMR Solvents, NMR Solvents and Reagents,
InChI Key   OKKJLVBELUTLKV-MZCSYVLQSA-N
isotopic purity   ≥99.8 atom % D
assay   ≥99% (CP)
contains   0.05 % (v/v) TMS
expl. lim.   5.5-36.5 % ((lit.))
impurities   ≤0.025% water
water
refractive index   n20/D 1.326 (lit.)
bp   65.4 °C(lit.)
mp   -99 °C (lit.)
density   0.888 g/mL at 25 °C (lit.)

Description

General description

Methanol-d4 (CD3OD) is a deuterated NMR solvent containing 0.05% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. Absolute infrared absorption intensities of CD3OD have been reported between 8000 and 350cm-1.

Application

Methanol-d4 may be used as a solvent to analyze the rate of exchange of methoxyl group in camphor and norcamphor dimethyl ketals.

Packaging

10, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN1230 - class 3 - PG 2 - Methanol
WGK Germany 
2
Flash Point(F) 
51.8 °F
Flash Point(C) 
11 °C

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Protocols & Articles

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Peer-Reviewed Papers
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