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639346 Sigma-Aldrich

tert-Butyldiisopropylphosphine

97%

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   97%
bp   77-79 °C/10 mmHg (lit.)
density   0.837 g/mL at 25 °C (lit.)
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   CC(C)P(C(C)C)C(C)(C)C
InChI   1S/C10H23P/c1-8(2)11(9(3)4)10(5,6)7/h8-9H,1-7H3
InChI key   OLSMQSZDUXXYAY-UHFFFAOYSA-N

Description

General description

tert-Butyldiisopropylphosphine is a phosphine ligand that can be utilized in C-C bond forming reactions.

Application

• Monodentate P-Donor Ligand
• Catalyst for selective propylene dimerization to dimethylbutenes

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2845 4.2
WGK Germany 
3
Protocols & Articles
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