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640360 Sigma-Aldrich

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

  • CAS Number 32679-02-0

  • Empirical Formula (Hill Notation) C12H18BF4N2Rh

  • Molecular Weight 379.99

  •  MDL number MFCD06798085

  •  PubChem Substance ID 24883086

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts More...
Quality Level   100
reaction suitability   reagent type: catalyst
SMILES string   [Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
InChI   1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
InChI key   KSMAFOANQHYEJG-SUESZSCISA-N

Description

Application

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)2]BF4 may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Catalysts
Protocols & Articles
Peer-Reviewed Papers
15

References

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