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  • 640697 - (1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene

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640697 Sigma-Aldrich

(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene

Synonym: (1E,3Z)-1-Methoxy-2-methyl-3-[(trimethylsilyl)oxy]-penta-1,3-diene, [(1-(2-Methoxy-1-methylvinyl)propenyloxy]trimethylsilan

  • CAS Number 72486-93-2

  • Empirical Formula (Hill Notation) C10H20O2Si

  • Molecular Weight 200.35

  •  MDL number MFCD10567404

  •  PubChem Substance ID 24882659

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
InChI Key   SSGAQVOLXCOJGN-AZRUORMVSA-N
refractive index   n20/D 1.4650(lit.)
bp   65 °C/6 mmHg(lit.)
density   0.899 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

1, 5 g in glass bottle

Application

Danishefsky diene used as a reactant for:
Preparation of migrastatin analog as cell migration inhibitor for treatment of tumor metastasis
Preparation of dihydropyridinones by chlorosilane-promoted aza-Diels-Alder addition
Synthesis on non-proteinogenic amino esters via stereoselective Lewis acid-catalyzed aza-Diels-Alder cycloaddition with conjugated (cyclo)dienes

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
WGK Germany 
3
Flash Point(F) 
177.8 °F
Flash Point(C) 
81 °C

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