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650412 Sigma-Aldrich

Borane tetrahydrofuran complex solution

1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

  • CAS Number 14044-65-6

  • Linear Formula BH3OC4H8

  • Molecular Weight 85.94

  •  Beilstein/REAXYS Number 3668402

  •  MDL number MFCD00012429

  •  PubChem Substance ID 24883750

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Properties

Related Categories 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction,
contains   0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer
concentration   1.0 M in THF
density   0.880 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   B.C1CCOC1
InChI   1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3
InChI key   RMCYTHFAWCWRFA-UHFFFAOYSA-N

Description

Application

New, Safer, NIMBA-Stabilized BH3 THF Solutions

This useful reagent for reductions and other transformations is now safer in transport utilizing this new stabilizer

Used to reduce nylon surface amide groups to secondary amines.

Packaging

4×25, 100, 800 mL in Sure/Seal™

8, 18 L in Kilo-Lab™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

View returnable container options.

Legal Information

U.S. Pat. No. 7,767,833.

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

BH3 THF Solutions | Technical Article

As part of our ongoing commitment to safety, we now offer a NIMBA-stabilized BH3-THF solution. All pack sizes offered (800 mL, 1L, 8L, 18L, and bulk) meet Self-Accelerated Decomposition Temperature (...

NIMBA-Stabilized BH3-THF

Borane-THF has long been a reagent of tremendous importance to synthetic organic chemists, utilized in reduction and hydroboration-oxidation as well as other transformations.1,2 As part of our ongoin...
Chemfiles Volume 5 Article 9
Keywords: Applications, Asymmetric synthesis, Degradations, Evaporation, Organic synthesis, Oxidations, Reductions

Related Content

NIMBA-stabilized BH3-THF Solutions

As part of our ongoing commitment to safety, we now offer a NIMBA-stabilized BH3-THF solution. This solution has a practical advantage in that all pack sizes offered (800 mL, 1L, 8L, 18L, and bulk) m...

Peer-Reviewed Papers
15

References

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