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650854 Sigma-Aldrich

(R)-BINAPHANE

Synonym: (R,R)-1,2-Bis[(R)-4,5-dihydro-3H-binaphtho(1,2-c:2′,1′-e)phosphepino]benzene

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes More...
InChI Key   CQYMOICHLLQQAH-UHFFFAOYSA-N
mp   >200 °C (dec.)

Description

Application

(R)-Binaphane shows excellent enantioselectivity (up to >99% ee) for hydrogenation of E/Z-isomeric mixtures of β-substituted arylenamides.

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Catalyst involved in:
• Enantioselective anilinosulfonamide allyl alcohol cyclization
• Synthesis of β-trifluoromethyl α-amino acids
• Phosphine-catalyzed cycloadditions of aldehydes and ketoketenes
• Dimerization of ketoketenes
• Enantioselective carbonyl-ene reactions via palladium and platinum derivatives

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

ChiralQuest Phosphine Ligands - Aldrich ChemFiles 2006, 6.8, 10.

One of the most efficient methods for constructing chiral compounds is asymmetric hydrogenation. Catalytic asymmetric hydrogenations are among the most widely used industrial catalytic processes, due...
Aldrich ChemFiles 2006, 6.8, 10.
Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Chemfiles, Hydrogenations, Ligands, Methods, Reductions, transformation

ChiralQuest Phosphine Ligands - ChemFiles Volume 5 Article 10

The field of asymmetric catalysis has been primarily represented by methodologies that have focused on incorporating hydrogen in a stereoselective manner into achiral molecules, especially in industr...
ChemFiles Volume 5 Article 10
Keywords: Applications, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, Reductions, transformation

Related Content

Chiral Quest Phosphine Ligands in chemical Synthesis

One of the most efficient methods for constructing chiral compounds is asymmetric hydrogenation. Catalytic asymmetric hydrogenations are among the most widely used industrial catalytic processes, due...
Keywords: Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, Reductions, transformation

Peer-Reviewed Papers
15

References

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