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654159 Sigma-Aldrich

Bis[(diphenylphosphanyl)methyl]amine palladium(II) acetate, polymer-bound

70-90 mesh particle size, extent of labeling: 0.5-1.0 mmol/g Pd loading, 1 % cross-linked with divinylbenzene

Synonym: Diacetobis[(diphenylphosphanyl)methyl]amine palladium(II), polymer-bound

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Palladium Catalysts, Supported Pd Catalysts
crosslinking   1 % cross-linked with divinylbenzene
reaction suitability   core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
extent of labeling   0.5-1.0 mmol/g Pd loading
particle size   70-90 mesh
storage temp.   room temp

Description

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Sonogashira Coupling Catalyzed by Palladium on Polymer Supports

Supported palladium catalysts are widely used in the Suzuki, Heck, and Sonogashira cross-coupling reactions. The advantages to using supported catalysts in organic synthesis include reagent stability...
Chemfiles Volume 5 Article 11
Keywords: Chromatography, Coupling reactions, Cross couplings, Flash chromatography, Organic synthesis, Sonogashira Coupling

Supported/Encapsulated Palladium Catalysts

Palladium has become one of the most commonly used metal for cross-coupling transformations. However, the use of homogeneous palladium presents several drawbacks that can be overcome by attaching the...
William Sommer
Aldrich ChemFiles 2007, 7.10, 23.
Keywords: Carbonylations, Catalysis, Chemfiles, Coupling reactions, Cross couplings, Immobilization, Ligands

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