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655406 Sigma-Aldrich

2-(2-Dicyclohexylphosphinophenyl)-1,3-dioxolane

97%

Synonym: Dicyclohexyl(2-(1,3-dioxolan-2-yl)phenyl)phosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands, Symphos More...
assay   97%
reaction suitability   reagent type: ligand
mp   82-85 °C (lit.)
functional group   phosphine
storage temp.   room temp
SMILES string   C1CCC(CC1)P(C2CCCCC2)c3ccccc3C4OCCO4
InChI   1S/C21H31O2P/c1-3-9-17(10-4-1)24(18-11-5-2-6-12-18)20-14-8-7-13-19(20)21-22-15-16-23-21/h7-8,13-14,17-18,21H,1-6,9-12,15-16H2
InChI key   DIFRDTMQEINUSG-UHFFFAOYSA-N

Description

Application

• Ligand for preparation of palladium P,O-ligand-catalyst for Suzuki cross-coupling reactions

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Chiral Phosphoric Acids

BINOL-derived phosphoric acids are capable of catalyzing a range of interesting processes of which nucleophilic addition reactions to imine substrates are particularly noteworthy. List and coworkers ...
Aldrich ChemFiles 2007, 7.9, 11.
Keywords: Addition reactions, Aminations, Asymmetric synthesis, Catalysis, Chemfiles, Diels-Alder reaction, Nucleophilic additions, Pictet-Spengler reaction, Reductions, Reductive aminations

Symphos

A new class of phenyl-backbone derived P,O-ligands (Symphos) were developed by Symyx Technologies in collaboration with professor Fu and coworkers.1 These new ligands proved to be suitable for genera...
William Sommer
Aldrich ChemFiles 2007, 7.10, 11.
Keywords: Catalysis, Chemfiles, Cross couplings, Ligands

Related Content

Symphos Ligands for Efficient Suzuki Cross Coupling

A new class of phenyl-backbone derived P,O-ligands (Symphos) were developed by Symyx Technologies in collaboration with professor Fu and co-workers.1 These new ligands proved to be suitable for gener...
Keywords: Catalysis, Cross couplings, Ligands

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