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656577 Aldrich

1,3-Diisopropylimidazolium chloride Green Alternative

97%

Synonym: N,N′-(Isopropyl)imidazolium chloride

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Properties

Related Categories 12 Principles Aligned Products, Carbon-Donor Ligands, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis,
InChI Key   DOFXKPAOJLLPII-UHFFFAOYSA-M
assay   97%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   182-186 °C

Description

Packaging

1, 5 g in glass bottle

Application

1,3-Diisopropylimidazolium chloride may be used to prepare:
• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
• (C9H7)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Protocols

Bestmann-Ohira Reagent: Synthesis of Alkynes from Aldehydes Protocol

Acetylene chemistry has been and remains an important constituent element of molecular sciences. Its potential and widespread applications extend from organic synthesis through materials science to b...
Keywords: Bestmann-Ohira Reaction, Building blocks, Chromatography, Click chemistry, Eliminations, Evaporation, Materials Science, Metallations, Organic synthesis, Thin layer chromatography

Catalytic Amide Bond Formation: Greener Methods

The amide bond is one of the most important linkages in organic chemistry and constitutes the key functional group in peptides, polymers, and many natural products and pharmaceuticals.  Amides are us...
Keywords: Amidations, Beckmann Rearrangement, Catalysis, Chromatography, Column chromatography, Ligands, Peptide synthesis, Pharmaceutical, Rearrangements, Schmidt Reaction, transformation

Peer-Reviewed Papers
15

References

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