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  • 65677 - (R)-1-{(RP)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine

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65677 Sigma-Aldrich

(R)-1-{(RP)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine

≥97%

Synonym: (1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]phenyl]ferrocene (acc to CAS), Walphos SL-W005-1

  • CAS Number 494227-30-4

  • Empirical Formula (Hill Notation) C52H44F12FeO2P2

  • Molecular Weight 1046.68

  •  MDL number MFCD04117708

  •  PubChem Substance ID 24884231

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Solvias Ligands and Complexes,
assay   ≥97%
optical purity   ee: ≥99%
storage temp.   2-8°C
SMILES string   [Fe].[CH]1[CH][CH][CH][CH]1.COc2c(C)cc(cc2C)P(c3cc(C)c(OC)c(C)c3)c4ccccc4[C]5[CH][CH][CH][C]5[C@@H](C)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
InChI   1S/C47H39F12O2P2.C5H5.Fe/c1-25-15-34(16-26(2)42(25)60-6)63(35-17-27(3)43(61-7)28(4)18-35)41-14-9-8-11-40(41)39-13-10-12-38(39)29(5)62(36-21-30(44(48,49)50)19-31(22-36)45(51,52)53)37-23-32(46(54,55)56)20-33(24-37)47(57,58)59;1-2-4-5-3-1;/h8-24,29H,1-7H3;1-5H;/t29-;;/m1../s1
InChI key   LYSMTOMQQHQCKG-SYXKTQFYSA-N

Description

General description

sold in collaboration with Solvias AG

Packaging

1, 5 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Solvias Ferrocenyl-Based Ligands

Solvias AG has demonstrated the incredible utility of chiral ferrocenyl diphosphine ligands in a wide range of reaction paradigms ranging from hydrogenation1 to the aldol reaction2 to hydroboration.3...
Aldrich ChemFiles 2006, 6.8, 12.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chemfiles, Grignard Reaction, Hydrogenations, Ligands, Type

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Solvias Chiral Phosphine Ligands - Toolkit for Asymmetric Catalysis

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Keywords: Asymmetric catalysis, Asymmetric synthesis, Catalysis, Individual protein Immunoprecipitation, Ligands

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