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660361 Sigma-Aldrich

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)

98%

Synonym: (NHC)Pd(allyl)Cl, Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium(II), CX 21

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, NHC-based Palladium Catalysts, Palladium Catalysts More...
InChI Key   YVIDBHQABBIAAW-UHFFFAOYSA-M
assay   98%
mp   >300 °C

Description

General description

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.

Legal Information

Sold in cooperation with Umicore for research purposes only. US Patent US 6,316,380; EP 721 953, and foreign equivalents apply

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

NHC-Based Pd Catalysts and Ligands for C–C Bond Formation

Sigma-Aldrich, in collaboration with Umicore,1 is pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as efficient catalysts in C–C bond forming reactions. The high performance Pd...
Aldrich ChemFiles 2006, 6.1, 8.
Keywords: Applications, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Coupling reactions, Ligands

NHC-based Palladium Catalysts

In collaboration with Umicore AG and Co.,1 we are pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as the linchpin in C–C bond forming reactions. The high performance Pd cataly...
William Sommer
ChemFiles 2007, 7.10, 19.
Keywords: Arylations, Building blocks, C-C bond formation, Catalysis, Coupling reactions, Suzuki-Miyaura coupling

Peer-Reviewed Papers
15

References

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