• USA Home
  • 660388 - 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0) dimer

EMAIL THIS PAGE TO A FRIEND
660388 Sigma-Aldrich

1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0) dimer

Synonym: Naphthoquinone-1,3-bis(2,6-diisopropylphenyl)-imidazole-2-ylidene-palladium(0) dimer, CX 11

  • CAS Number 649736-75-4

  • Empirical Formula (Hill Notation) C74H84N4O4Pd2

  • Molecular Weight 1306.32

  •  PubChem Substance ID 329760156

  •  NACRES NA.22

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, NHC-based Palladium Catalysts, Palladium Catalysts More...
Quality Level   100
reaction suitability   core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
mp   >300 °C
SMILES string   O=C1C=CC(=O)c2ccccc12.O=C3C=CC(=O)c4ccccc34.CC(C)c5cccc(C(C)C)c5N6C=CN(C6[Pd])c7c(cccc7C(C)C)C(C)C.CC(C)c8cccc(C(C)C)c8N9C=CN(C9[Pd])c%10c(cccc%10C(C)C)C(C)C
InChI   1S/2C27H37N2.2C10H6O2.2Pd/c2*1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2*11-9-5-6-10(12)8-4-2-1-3-7(8)9;;/h2*9-21H,1-8H3;2*1-6H;;
InChI key   SQNPUPJPLWQFHN-UHFFFAOYSA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Legal Information

Sold in cooperation with Umicore for research purposes only. US Patent US 6,316,380; WO2004014550, and foreign equivalents apply.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

NHC-Based Pd Catalysts and Ligands for C–C Bond Formation

In collaboration with Umicore,1 we are pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as efficient catalysts in C–C bond forming reactions. The high performance Pd catalysts ...
ChemFiles 2006, 6.1, 8.
Keywords: Arylations, Asymmetric synthesis, Building blocks, C-C bond formation, Catalysis, Coupling reactions, Ligands, Suzuki-Miyaura coupling

NHC-based Palladium Catalysts

In collaboration with Umicore AG and Co.,1 we are pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as the linchpin in C–C bond forming reactions. The high performance Pd cataly...
William Sommer
ChemFiles 2007, 7.10, 19.
Keywords: Arylations, Building blocks, C-C bond formation, Catalysis, Coupling reactions, Suzuki-Miyaura coupling

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?