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661708 Sigma-Aldrich

(R)-(−)-COP-OAc Catalyst

95%

Synonym: Di-μ-acetatobis[η5-(R)-(pR)-2-(2′-(4′-methylethyl)oxazolinyl)cyclopentadienyl,1-C,3′-N)(η4-tetraphenylcyclobutadiene)cobalt]dipalladium

  • CAS Number 849592-74-1

  • Empirical Formula (Hill Notation) C82H72O6N2Co2Pd2

  • Molecular Weight 1512.17

  •  PubChem Substance ID 24884539

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Rearrangement Reaction
assay   95%
mp   241-251 °C (dec.)
SMILES string   [Co].[Co].CC(=O)[O+]1[Pd-][O+]([Pd-]1)C(C)=O.CC(C)[C@@H]2COC(=N2)[C]3[CH][CH][CH][CH]3.CC(C)[C@@H]4COC(=N4)[C]5[CH][CH][CH][CH]5.c6ccc(cc6)[C]7[C]([C]([C]7c8ccccc8)c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)[C]%12[C]([C]([C]%12c%13ccccc%13)c%14ccccc%14)c%15ccccc%15
InChI   1S/2C28H20.2C11H14NO.2C2H3O2.2Co.2Pd/c2*1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22)28(24-19-11-4-12-20-24)27(25)23-17-9-3-10-18-23;2*1-8(2)10-7-13-11(12-10)9-5-3-4-6-9;2*1-2(3)4;;;;/h2*1-20H;2*3-6,8,10H,7H2,1-2H3;2*1H3;;;;/q;;;;2*+1;;;2*-1/t;;2*10-;;;;;;/m..00....../s1
InChI key   WZRJKKZQBPMZCQ-TWWPWAOZSA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Catalyst used for the synthesis of chiral allylic ethers.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Asymmetric Allylation Using COP Catalysts

Chiral allylic aryl esters are valuable building blocks for the synthesis of natural products and drug candidates. In recent years, several research groups developed new catalysts to synthesize chira...
William Sommer
Aldrich ChemFiles 2008, 8.6, 6.
Keywords: Building blocks, Chemfiles

Peer-Reviewed Papers
15

References

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