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661910 Sigma-Aldrich

(R)-(−)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid

96%

Synonym: (R)-(−)-2-(tert-Butyl)-3-methyl-4-oxoimidazolidinium trifluoroacetate, (R)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid salt

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MacMillan Imidazolidinone OrganoCatalysts
InChI Key   HKHKOEMMPVPVOS-OGFXRTJISA-N
assay   96%
mp   99-103 °C
storage temp.   2-8°C

Description

Packaging

2 g in glass bottle

500 mg in glass bottle

Application

Highly selective organocatalyst for 1,3-dipolar addition and Friedel-Crafts alkylation.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
2

Documents

Certificate of Analysis

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Protocols & Articles

Articles

MacMillan Imidazolidinone OrganoCatalysts™ | Aldrich ChemFiles 2007, 7.9, 8.

Developed by Professor David MacMillan at Caltech, imidazolidinone based OrganoCatalysts™ are designed to serve as general catalysts for a myriad of asymmetric transformations. The first highly enant...
Aldrich ChemFiles 2007, 7.9, 8.
Keywords: Alkylations, Asymmetric synthesis, Chemfiles, Chlorinations, Condensations, Cycloadditions, Fluorinations, Formulations, Hydrogenations, Reductions

Related Content

Macmillan Imidazolidinone Organocatalysts in Chemical Sythesis

Developed by Professor David MacMillan at Caltech, imidazolidinone-based OrganoCatalysts are designed to serve as general catalysts for a variety of asymmetric transformations. The first highly enant...
Keywords: Alkylations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Chlorinations, Condensations, Cycloadditions, Diels-Alder reaction, Fluorinations, Friedel-Crafts Alkylation

Peer-Reviewed Papers
15

References

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