• USA Home
  • 662992 - trans-1-Hepten-1-ylboronic acid pinacol ester

EMAIL THIS PAGE TO A FRIEND
662992 Sigma-Aldrich

trans-1-Hepten-1-ylboronic acid pinacol ester

97%

Synonym: E-2-(1-Heptenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, trans-1-Heptenylboronic acid pinacol ester

Purchase

Properties

Related Categories Alkenyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   XHEDFAYNMNXKGM-ZHACJKMWSA-N
assay   97%
refractive index   n20/D 1.445
bp   73-77 °C/0.4-0.5 mmHg
density   0.875 g/mL at 25 °C

Description

Packaging

5 g in glass bottle

Application

Substrate used in a palladium-catalyzed cross-coupling with olefins providing substituted 1,3-dienes.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
222.8 °F
Flash Point(C) 
106 °C
Protocols & Articles

Articles

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions, Suzuki-Miyaura coupling

Suzuki Coupling | ChemFiles 2006, 6.2, 10.

C–C bond formation via the Suzuki–Miyaura reaction is one of the most powerful and thoroughly explored facets of Pdcatalyzed cross-coupling. The boron-based nucleophiles utilized in this reaction off...
ChemFiles 2006, 6.2, 10.
Keywords: Addition reactions, C-C bond formation, Coupling reactions, Cross couplings, Epoxidations, Halogenations, Ligands, Microwave synthesis, Ozonolysis, Suzuki coupling, Vinylations

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?