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  • 663085 - (5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid

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663085 Sigma-Aldrich

(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid

97%

Synonym: (5S)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone dichloroacetic acid

  • CAS Number 345358-20-5

  • Empirical Formula (Hill Notation) C15H20Cl2N2O3

  • Molecular Weight 347.24

  •  MDL number MFCD08276841

  •  PubChem Substance ID 24884183

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MacMillan Imidazolidinone OrganoCatalysts
assay   97%
mp   122-126 °C
SMILES string   OC(=O)C(Cl)Cl.CN1C(=O)[C@H](Cc2ccccc2)NC1(C)C
InChI   1S/C13H18N2O.C2H2Cl2O2/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;3-1(4)2(5)6/h4-8,11,14H,9H2,1-3H3;1H,(H,5,6)/t11-;/m0./s1
InChI key   YZRAPAXOLQHZSE-MERQFXBCSA-N

Description

Packaging

2 g in glass bottle

500 mg in glass insert

Application

Utilized in the first example of organocatalytic enantioselective α-fluorination of aldehydes.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Related Content

Macmillan Imidazolidinone Organocatalysts in Chemical Sythesis

Developed by Professor David MacMillan at Caltech, imidazolidinone-based OrganoCatalysts are designed to serve as general catalysts for a variety of asymmetric transformations. The first highly enant...
Keywords: Alkylations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Chlorinations, Condensations, Cycloadditions, Diels-Alder reaction, Fluorinations, Friedel-Crafts Alkylation

Peer-Reviewed Papers
15

References

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