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663743 Sigma-Aldrich

trans-1-Hexen-1-ylboronic acid pinacol ester

97%

Synonym: (E)-2-(1-Hexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, trans-1-Hexenylboronic acid pinacol ester

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Properties

Related Categories Alkenyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents More...
InChI Key   PAOJMGKYYPHNDO-MDZDMXLPSA-N
assay   97%
refractive index   n20/D 1.443
bp   62-65 °C/0.5-0.6 mmHg
density   0.875 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
195.8 °F
Flash Point(C) 
91 °C
Protocols & Articles

Articles

Boronic Acid Esters - Chemfiles Volume 4 Article 2

The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available. Several years ago, Miyaura et al. demonst...
Chemfiles Volume 4 Article 2
Keywords: Coupling reactions, Suzuki-Miyaura coupling

Suzuki Coupling | ChemFiles 2006, 6.2, 10.

C–C bond formation via the Suzuki–Miyaura reaction is one of the most powerful and thoroughly explored facets of Pdcatalyzed cross-coupling. The boron-based nucleophiles utilized in this reaction off...
ChemFiles 2006, 6.2, 10.
Keywords: Addition reactions, C-C bond formation, Coupling reactions, Cross couplings, Epoxidations, Halogenations, Ligands, Microwave synthesis, Ozonolysis, Suzuki coupling, Vinylations

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